Danel Sinani and Oliver Skipp featured for Luxembourg and England Under-21s respectively on Tuesday evening.
The former played the full 90 minutes and missed a penalty as Luxembourg drew 0-0 with Azerbaijan to finish their UEFA Nations League group in second.
England’s U21s had a better result, beating Albania U21s 5-0 at the Molineux Stadium, with Skipp playing for the first 76 minutes.
The win means that England end their UEFA Euro 2020 Under-21 qualifying group in first, ten points clear of Austria U21s.